Photoacoustic infrared spectroscopy for conducting gas tracer tests and measuring water saturations in landfills

Gas tracer tests can be used to determine gas flow patterns within landfills, quantify volatile contaminant residence time, and measure water within refuse. While gas chromatography (GC) has been traditionally used to analyze gas tracers in refuse, photoacoustic spectroscopy (PAS) might allow real-time measurements with reduced personnel costs and greater mobility and ease of use. Laboratory and field experiments were conducted to evaluate the efficacy of PAS for conducting gas tracer tests in landfills. Two tracer gases, difluoromethane (DFM) and sulfur hexafluoride (SF₆), were measured with a commercial PAS instrument. Relative measurement errors were invariant with tracer concentration but influenced by background gas: errors were 1-3% in landfill gas but 4-5% in air. Two partitioning gas tracer tests were conducted in an aerobic landfill, and limits of detection (LODs) were 3-4 times larger for DFM with PAS versus GC due to temporal changes in background signals. While higher LODs can be compensated by injecting larger tracer mass, changes in background signals increased the uncertainty in measured water saturations by up to 25% over comparable GC methods. PAS has distinct advantages over GC with respect to personnel costs and ease of use, although for field applications GC analyses of select samples are recommended to quantify instrument interferences.     

Rubber tire life cycle assessment and the effect of reducing carbon footprint by replacing carbon black with graphene

This research utilizes real operating data from a tire plant operating in Central Taiwan to investigate the carbon footprint emissions (CO₂e) involved in producing the electric bicycle. The simulation results are based on the PAS 2050 standard using the SimaPro 7.3 software tool. Our results show the total carbon footprint emissions of 1.2-kg tire for the electric bicycle weighing 4.53-kg CO₂e, composed of 2.63-kg CO₂e from raw tire materials stage, 1.295-kg CO₂e from tire manufacturing stage, and 0.605-kg CO₂e from tire transport stage. An international certified organization, British Standard Institute (BSI), verified the accuracy of our results as 98.7%. We found that carbon emissions at the raw materials stage were higher than that for the other two stages – manufacturing and transportation. Carbon black was determined as the maximum source of carbon emissions at the raw material stage. To reduce the tire plant carbon emissions, this paper recommends using graphene to replace carbon black. Graphene has been reported by many researches to improve the properties of rubber products. From our simulation results, the carbon footprint emissions of 4.56-kg CO₂e of the origin tire plant uses 0.456-kg carbon black to produce 1.2-kg electric bicycle tires. This can be reduced to 4.29 (5.92%), 4.03 (11.62%), 3.75 (11.76%), and 3.49-kg CO₂e (23.46%) by using graphene to replace carbon black 25, 50, 75, and 100 wt% respectively. If we focus only on 0.456-kg carbon black producing 1.08-kg CO₂e, the reduced carbon footprint will be 0.812 (24.81%), 0.547 (49.35%), 0.28 (74.07%), and 0.0128-kg CO₂e (98.81%) by using graphene to replace carbon black 25, 50, 75, and 100 wt% respectively. From our analysis, graphene replacing carbon black can reduce carbon footprint. This has not been published previously and provides a direction for the tire plant to save carbon emissions.     

Constituents of volatile organic compounds of evaporating essential oil

Essential oils containing aromatic compounds can affect air quality when used indoors. Five typical and popular essential oils—rose, lemon, rosemary, tea tree and lavender—were investigated in terms of composition, thermal characteristics, volatile organic compound (VOC) constituents, and emission factors. The activation energy was 6.3–8.6 kcal mol^?1, the reaction order was in the range of 0.6–0.8, and the frequency factor was 0.01–0.24 min^?1. Toluene, 1,2,3-trimethylbenzene, 1,2,4-trimethylbenzene, n-undecane, p-diethylbenzene and m-diethylbenzene were the predominant VOCs of evaporating gas of essential oils at 40 °C. In addition, n-undecane, p-diethylbenzene, 1,2,4-trimethylbenzene, m-diethylbenzene, and 1,2,3-trimethylbenzene revealed high emission factors during the thermogravimetric (TG) analysis procedures. The sequence of the emission factors of 52 VOCs (137–173 mg g^?1) was rose ≈ rosemary > tea tree ≈ lemon ≈ lavender. The VOC group fraction of the emission factor of aromatics was 62–78%, paraffins were 21–37% and olefins were less than 1.5% during the TG process. Some unhealthy VOCs such as benzene and toluene were measured at low temperature; they reveal the potential effect on indoor air quality and human health.     

Partitioning Gas Tracer Tests for Measurement of Water in Municipal Solid Waste

Abstract

A key component in the operation of almost all bioreactor landfills is the addition of water to maintain optimal moisture conditions. To determine how much water is needed and where to add it, in situ methods are required to measure water within solid waste. Existing technologies often result in measurements of unknown accuracy, because of the variability of solid waste materials and time-dependent changes in packing density, both of which influence most measurement methods. To overcome these problems, a new technology recently developed by hydrologists for measuring water in the vadose zone—the partitioning gas tracer test—was tested. In this technology, the transport behavior of two gas tracers within solid waste is used to measure the fraction of the void space filled with water. One tracer is conservative and does not react with solids or liquids, while a second tracer partitions into the water and is separated from the conservative tracer during transport. This technology was tested in four different solid waste packings and was capable of determining the volumetric water content to within 48% of actual values, with most measurement errors less than 15%. This technology and the factors that affect its applicability to landfills are discussed in this paper.     

Emission factor of exhaust gas constituents during the pyrolysis of zinc chloride immersed biosolid

Pyrolysis enables ZnCl₂ immersed biosolid to be reused, but some hazardous air pollutants are emitted during this process. Physical characteristics of biosolid adsorbents were investigated in this work. In addition, the constituents of pyrolytic exhaust were determined to evaluate the exhaust characteristics. Results indicated that the pyrolytic temperature was higher than 500 °C, the specific surface area was >900 m²/g, and the total pore volume was as much as 0.8 cm³/g at 600 °C. For non-ZnCl₂ immersed biosolid pyrolytic exhaust, VOC emission factors increased from 0.677 to 3.170 mg-VOCs/g-biosolid with the pyrolytic temperature increase from 400 to 700 °C, and chlorinated VOCs and oxygenated VOCs were the dominant fraction of VOC groups. VOC emission factors increased about three to seven times, ranging from 1.813 to 21.448 mg/g for pyrolytic temperatures at 400–700 °C, corresponding to the mass ratio of ZnCl₂ and biosolid ranging from 0.25–2.5.     

Postnatal management and long-term outcome for survivors with congenital diaphragmatic hernia

Significant advances in the postnatal management of patients with congenital diaphragmatic hernia (CDH) have resulted in a remarkable improvement in survival rates over the past two decades. The success of current postnatal management of CDH patients has rendered fetal intervention to be limited to the most severe cases, and the role for prenatal treatment of CDH patients remains unclear. The adoption of lung-preserving strategies including high-frequency oscillatory ventilation (HFOV) and extracorporeal membrane oxygenation (ECMO) have improved CDH outcomes especially in those patients with significant ventilatory or circulatory compromise. Survival rates of up to 90% are being reported in some high-volume centers. However, the increased survival in CDH patients has been accompanied by an increase in neurological, nutritional and musculoskeletal morbidity among the long-term survivors. This has resulted in the need to provide resources for the long-term follow-up and support of this patient population. In this article, the postnatal management strategies and primary and secondary outcomes of high-volume international pediatric surgical centers will be reviewed. Finally, the role of a multidisciplinary management team for the follow-up of long-term CDH survivors will be discussed. Copyright © 2008 John Wiley & Sons, Ltd.     

Characterization of contamination in and toxicities of a shipyard area in Hong Kong

This is the first integrated study on the contaminant characterization and toxicities of a shipyard area. This site in Hong Kong contained 3.6-33.4 mg kg(-1) dichlorodiphenyltrichloroethane and 5-79 g kg(-1) oil and grease. Other pollutants exceeding the Dutch intervention values were total polyaromatic hydrocarbons, total petroleum hydrocarbons, and metals Cu, Pb and Zn. These pollutants persisted partially owing to the poor fertility with <125 mg N kg(-1) and <530 mg P kg(-1) typical of coastal soil. Sediments collected within 100 m also showed contamination exceeding the China and Hong Kong intervention levels. The shipyard soil killed two bacteria Pseudomonas stutzeri and Acinetobacter sp. isolated from a clean coastal soil, inhibited germination of three exogenous plants Triticum aestivum, Brassica chinense and Lolium perenne, and inhibited proliferation of three indigenous bacteria: Methylobacterium sp., Pseudomonas aeruginosa and Bacillus cereus. Thus, ex situ remediation was needed.     

Water-soluble ions in nano/ultrafine/fine/coarse particles collected near a busy road and at a rural site

This study investigated water-soluble ions in the sized particles (particularly nano (PM(0.01-0.056))/ultrafine (PM(0.01-0.1))) collected using MOUDI and Nano-MOUDI samplers near a busy road site and at a rural site. The analytical results demonstrate that nano and coarse particles exhibited the highest (16.3%) and lowest (8.37%) nitrate mass ratios, respectively. The mass ratio of NO(3)(-) was higher than that of SO(4)(2-) in all the sized particles at the traffic site. The secondary aerosols all displayed trimodal distributions. The aerosols in ultrafine particles collected at the roadside site exhibited Aitken mode distributions indicating they were of local origin. This finding was not observed for those ultrafine particles collected at the rural site. The mass median diameters (MMDs) of the nano, ultrafine, and fine particles were smaller at the traffic site than at the rural site, possibly related to the contribution of mobile engine emissions.